15.1- Thermodynamic Systems and Their Surroundings
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Thermodynamics is the branch of physics that is built upon the fundamental laws that heat and work obey.
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In thermodynamics, the collection of objects upon which attention is being focused is called the system, while everything else in the environment is called the surroundings.
15.2- The Zeroth Law Of Thermodynamics
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The zeroth law of thermodynamics deals with the concept of
thermal equilibrium, which occurs when there is no net flow of heat between two systems that are in contact.
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The
zeroth law of thermodynamics states that two systems individually in thermal equilibrium with a third system are in thermal equilibrium with each other.
15.3- The First Law of Thermodynamics
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The first law of thermodynamics states that heat is positive when a system gains heat and negative when a system loses heat and work is positive when it is done by the system and negative when it is done on the system.
15.7- The Second Law of Thermodynamics
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The
second law of thermodynamics is also known as the heat flow statement.
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The second law of thermodynamics states that heat flows spontaneously from a substance at a higher temperature to a substance at a lower temperature and does not flow spontaneously in the reverse direction.
15.11- Entropy and The Second Law of Thermodynamics
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Entropy is in closed thermodynamic system, a quantitative measure of the amount of thermal energy not available to do work. It is also known as the amount of disorder in a system.
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Reversible processes do not alter the total entropy of the universe.
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Any irreversible process increases the entropy of the universe.
15.12- The Third Law of Thermodynamics
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The
third law of thermodynamics states that it is not possible to lower the temperature of any system to absolute zero in a finite number of steps.